B型微晶山药淀粉的表征Characterization of B-Type Microcrystalline Yam Starch
周晓微,杭书扬,薛梦豪,张家瑞,刘延奇
摘要(Abstract):
为改善山药淀粉的性质,以山药淀粉为原料,在35℃条件下经盐酸(2.2 mol/L)水解96 h得酸解山药淀粉,再经溶解、离心和冷冻结晶得到微晶山药淀粉。通过对山药淀粉、酸解山药淀粉和微晶山药淀粉进行结构表征,得到结果:山药淀粉、酸解山药淀粉呈鹅卵石状,粒径约为5~25μm,微晶山药淀粉是直径3~8μm的球形颗粒;山药淀粉、酸解山药淀粉晶型为C型,结晶度分别为42.4%和45.1%,而微晶山药淀粉晶型为B型,结晶度提高至45.8%;酸解和结晶化处理未使淀粉引入新的官能团,但其短程有序性得到了进一步提升;与山药原淀粉相比,酸解山药淀粉和B型微晶山药淀粉的起始分解温度越来越低,分解速率最大时温度逐步上升,微晶淀粉的热稳定性提高;在微晶化过程中山药淀粉分子量不断减小,所形成的酸解淀粉和B型微晶淀粉的葡萄糖聚合度分别为123.27和49.55。
关键词(KeyWords): 山药淀粉;酸解淀粉;微晶淀粉;结晶度;短程有序性
基金项目(Foundation): 河南省自然科学基金项目(222300420580);; 河南省科技攻关项目(222102110337)
作者(Author): 周晓微,杭书扬,薛梦豪,张家瑞,刘延奇
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