含硫香料化合物3-甲硫基-1-己醇及其乙酸酯的合成研究Study on syntheses of sulfur-containing flavors 3-methylthio-1-hexanol and 3-methylthio-1-hexyl acetate
郭安齐
摘要(Abstract)：
以E-2-己烯醛为原料研究了3-甲硫基己醇及3-甲硫基乙酸己酯的合成方法。首先甲硫醇钠与E-2-己烯醛发生1,4-共轭加成得到3-甲硫基己醛,产率87%;然后用硼氢化钠还原得到3-甲硫基己醇,产率92%左右;3-甲硫基己醇在乙酸钠的催化下与乙酸酐反应,得到3-甲硫基乙酸己酯,产率约95%。产物结构经过GC/MS和1HNMR谱图进行了确认。
关键词(KeyWords)： 含硫香料;3-甲硫基-1-己醇;3-甲硫基乙酸己酯;合成
基金项目(Foundation):
作者(Author): 郭安齐
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